Metal-Organic Framework-Assisted Rational Design of Multicolor Solid-State Fluorescent Carbon Nanodots and Its Application for LEDs

Carbon nanodots (CDs) are a new type of carbon-based fluorescent nanomaterials, but they are limited in many applications due to the inherent fluorescence weakening and quenching problems suffered in solid state. Herein, ZIF-8, a class of metal-organic framework (MOF) is employed as a matrix to immobilize fluorescent CDs, resulting in the strong luminescence of CDs achieved in solid state. The as-synthesized CDs@ZIF-8 fluorescent powders possess blue, green, and red emissions with the main emission at approximate to 495, 528, and 600 nm, and the corresponding photoluminescence quantum yields (PLQYs) are as high as 25.89%, 52.24%, and 15.42%, respectively. It is found that the encapsulation of ZIF-8 with CDs will increase the excitation dependence of the product fluorescence, which may be attributed to the carrier effect of ZIF-8 as a carrier of CDs and some surface defects or surface functional groups change of the CDs introduced by ZIF-8. In addition, the encapsulation of CDs with ZIF-8 may result in the charge transfer. Importantly, the prepared CDs@ZIF-8 phosphors present a promising application in the fabrication of monochromatic light-emitting diodes (LEDs). The synthesis design is expected to provide technical support for future solid-state fluorescent CDs preparation and applications. ZIF-8 is employed as a matrix to immobilize fluorescent carbon nanodots (CDs), resulting in the strong luminescence of CDs achieved in solid state. The as-synthesized CDs@ZIF-8 fluorescent powders possess blue, green, and red emissions with the corresponding photoluminescence quantum yields (PLQYs) as high as 25.89%, 52.24% and 15.42%, respectively. The CDs@ZIF-8 phosphors present a promising application in monochromatic light-emitting diodes (LEDs).image