Micron-Sized Hierarchical Beta Zeolites Templated by Mesoscale Cationic Polymers as Robust Catalysts for Acylation of Anisole with Acetic Anhydride

Hierarchical Beta zeolites with interconnected intracrystalline mesopores and high structural stability are highly attractive for catalytic applications involving bulky reactants. Here, by introducing a suitable amount of polydiallyldimethylammonium chloride into the initial synthesis system, micron-sized Beta zeolite crystals with abundant hierarchical porosity (Beta-H) were hydrothermally synthesized. The sample named Beta-H_1 exhibited very high catalytic activity and durability for the Friedel-Crafts acylation of anisole with acetic anhydride. A 92% conversion rate of acetic anhydride could be achieved after 1 h of reaction in a fixed bed reactor, and 71% conversion still remained after 10 h, much better than the rate for conventional Beta zeolite (which decreased rapidly from 85% to 37% within 10 h). The enhanced catalytic performance of Beta-H zeolites could be mainly attributed to the relatively lower strong acid density and the faster transport rate of the hierarchical zeolites. In addition, Beta-H showed high structural stability and could be easily regenerated via high-temperature calcination without obvious loss in catalytic activity, demonstrating its great potential for catalytic applications in the industrially important Friedel-Crafts acylation process.