Inhibiting effect of 2-amino-2-methyl-1-propanol on gelatinous product formation in non-aqueous CO2 absorbents: Experimental study and molecular understanding

Diamines or polyamines with two or more amino groups are suitable for formulating non-aqueous absorbents (NAAs) with high CO2 loading capacity and low regeneration energy consumption. However, these two types of amines in NAAs are prone to produce insoluble gelatinous products after absorbing CO2, resulting in difficult operation of the CO2 capture system. In this study, by using 2-amino-2-methyl-1-propanol (AMP) as an inhibitor, the insoluble gelatinous products of the aminoethylethanolamine (AEEA)-N-methyl-2-pyrrolidone (NMP) (A -AN) and 3-(methylamino)propylamine (MAPA)-NMP (M-A-N) NAAs were successfully eliminated. The experimental results showed that the AMP-regulated NAAs possessed a high absorption rate, high CO2 loading capacity, excellent desorption efficiency, and stable recyclability. The reaction mechanism of CO2 absorption and the inhibitory mechanism of AMP on the formation of gelatinous products were comprehensively elucidated. Taking the A-A-N system as a representative, AEEA reacted with CO2 to form zwitterionic protonated carbamate species (AEEACO2 ?(P)H+(S)), which tended to self-aggregate via hydrogen-bond interaction, resulting in the formation of insoluble gelatinous products. With the introduction of AMP, the AMP-derived products could combine easily with AEEACO2 ?(P)H+(S) via strong electrostatic attraction to form ion pairs, preventing the AEEACO2 ?(P)H+(S) molecules from self-aggregating to form insoluble gelatinous products. The regeneration heat duty of the A-A-N system was 1.89 GJ center dot ton ? 1 CO2, which was 49.9 % lower than that of the benchmark 30 wt% MEA. Overall, introducing AMP as a gelatinous product inhibitor was beneficial for the development of NNAs with high CO2 absorption capacity and low-energy consumption.