Contribution of micropores in porous zirconia spheres to high optical transparency of dental resin composites

Transparency to UV-Vis light and radiopacity of dental resin composites containing zirconia (ZrO2) fillers were investigated. The transparency of the resin composite containing porous ZrO2 spheres was much higher than that containing irregularly shaped ZrO2 particles. Calcination of the porous ZrO2 spheres at high temperatures led to dramatically reduced specific surface areas and pore volumes. The transparency of the resin composite containing the calcined porous ZrO2 spheres drastically decreased as the calcination temperature increased. Then, the enhanced UV-Vis transmittance of the resin composite containing porous ZrO2 spheres is attributed to the concentration and physical characteristics of the pores. The radiopacity of the resin composites containing porous ZrO2 spheres increased slightly with increasing calcination temperature. This study revealed that the internal structure of the ZrO2 fillers mainly influenced in the UV-Vis light transmittance of the resin composites.