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Facile fabrication of bismuth vanadate grafted carbon nanotubes composite for enhanced oxygen evolution reaction

JOURNAL OF ELECTROANALYTICAL CHEMISTRY(2024)

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Abstract
The increasing demand of maintainable energy boosts researchers to develop reliable electrocatalysts for enhanced water splitting mechanisms. All the synthesized materials, including CNTs, BiVO4, and BiVO4/CNTs, were characterized utilizing a variety of methodologies to assist the structural, configurational, morphological, and topographical investigations. This work aims to create unique BiVO4/CNTs nanocomposite, which may have higher electrocatalytic activity then previous materials (81 mV dec-1 tafel slope and overpotential of 237 mV at 10 mAcm � 2). The composite exhibits notable qualities, including extended stability lasting up to 100 h, a substantial electrochemically active surface area (ECSA) of 586.5 cm2, minimal charge transfer resistance (Rct) of 1.3 omega, a low onset potential, a reasonably reduced overpotential, and a relatively modest Tafel slope. The synergistic interaction between CNTs and BiVO4 is responsible for electrocatalyst's exceptional catalytic efficiency and unique stability for 100-hour retaining both morphological and structural features, showcasing structural integrity of BiVO4/CNTs nano-composite. The objective of this research is to split water into its component molecules using a nano-composite made, and may also useful for future applications.
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Key words
Bismuth vanadate,Carbon nanotubes,Oxygen evolution reaction,Multimetal oxide,Carbon Support
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