Non-enzymatic Synthesis of C-Methylated Fluostatins: Discovery and Reaction Mechanism

Bidhan Chandra De,Chunfang Yang,Chunshuai Huang,Changsheng Zhang,Wenjun Zhang

Organic & Biomolecular Chemistry（2024）

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摘要

Two methylation FSTs, FST B3/FST B4 (1/2), were obtained from oxidative ring-opening reaction. The structure of 1/2 were elucidated by HRESIMS, 1D, 2D NMR spectra, and comparison of ECD spectra....

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