Sample preparation, analytical characterization, monitoring, risk assessment and treatment of naphthenic acids in industrial wastewater and surrounding water impacted by unconventional petroleum production

Industrial extraction of unconventional petroleum results in notable volumes of oil sands process water (OSPW), containing elevated concentrations of naphthenic acids (NAs). The presence of NAs represents an intricate amalgamation of dissolved organic constituents, thereby presenting a notable hurdle for the domain of environmental analytical chemistry. There is growing concern about monitoring the potential seepage of OSPW NAs into nearby groundwater and river water. This review summarizes recent studies on sample preparation, characterization, monitoring, risk assessment, and treatment of NAs in industrial wastewater and surrounding water. Sample preparation approaches, such as liquid-liquid extraction, solid phase microextraction, and solid phase extraction, are crucial in isolating chemical standards, performing molecular level analysis, assessing aquatic toxicity, monitoring, and treating OSPW. Instrument techniques for NAs analysis were reviewed to cover different injection modes, ionization sources, and mass analyzers. Recent studies of transfer and transformation of NAs provide insights to differentiate between anthropogenic and natural bitumen-derived sources of NAs. In addition, related risk assessment and treatment studies were also present for elucidation of environmental implication and reclamation strategies. The synthesis of the current state of scientific knowledge presented in this review targets government regulators, academic researchers, and industrial scientists with interests spanning analytical chemistry, toxicology, and wastewater management.