Positive effect of co-addition of Dy2O3/Ag and Dy2O3/WO3 nanoparticles on the physical critical parameters and electrical transport properties of YBCO ceramic

CERAMICS INTERNATIONAL(2024)

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摘要
In this study, YBa2Cu3O7-delta (YBCO) polycrystalline samples with co -addition of nanostructure materials (NSMs) of 0.1 wt% Dy2O3/Ag and 0.1 wt% Dy2O3/WO3 were synthesized via solid-state reaction sintering. Herein, the considered NSMs are of two shapes: nanoparticles (NPs) of dysprosium oxide and silver and nanowires of tungsten oxide. X-ray powder diffraction (XRD) and scanning electron microscopy (SEM) were used to examine the structure and morphology of samples. Resistivity versus temperature (p(T)), ac susceptibility (chi(T)), and dc magnetization (M(H)) measurements have been carried out on superconducting YBCO to deduce critical superconducting parameters like Bc1 and Jc. Using the Aslamazov-Larkin approach, the induced excess conductivity analysis was performed to complete values of critical lengths such as xi co, Ao, critical magnetic fields (Bc1, Bc2), and critical current density Jc at 0 K. The combined addition of Dy2O3/Ag and Dy2O3/WO3 conserves the orthorhombic structure, the grain size of about some micrometers, and the volume fraction of superconductor grain (Vsg%). NSMs co -addition ameliorates the assembly of grains and their connectivity to empower the carriers' charge transportation between the grains. Dy-rich entities are inserted into the YBCO grains' surfaces. The critical superconducting parameters Bco, Bc1, Bc2, and Jc are high in co -added samples due to the decrease in intergrain resistivity and the better competence of trapping flux lines inside the samples. The combination of different types of NSMs inside YBCO constitutes a hopeful way to compromise between better grain coupling and higher flux pinning. Ag NPs coupled with Dy2O3 NPs act more efficiently than WO3 NW coupled with Dy2O3 NPs in YBCO compounds to make its properties better.
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关键词
Flux trapping properties,Excess conductivity
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