Dual-path glucose electrooxidation reaction on Ni(OH)2/NiOOH catalysts in alkaline media

Alejandra Medrano-Banda, Julie Guehl,Gwénaëlle Kéranguéven,Alexandr Oshchepkov,Elena Savinova,Antoine Bonnefont

Electrochimica Acta（2024）

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摘要

•GOR in alkaline media is catalyzed by the Ni(OH)2/NiOOH transition but not the Ni/Ni(OH)2 one.•Presence of Fe impurities impacts the GOR on Ni(OH)2/NiOOH electrodes.•In-situ FTIRS confirms formate as one of the main products of the GOR on Ni.•Microkinetic modeling suggests that GOR on Ni occurs through a dual-path mechanism.

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关键词

Glucose oxidation reaction (GOR),Nickel hydroxide,Iron,In situ Fourier transform infrared spectroscopy (FTIRS),Meanfield kinetic modeling

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