Geochemical characteristics and genesis of the Ordovician sub-salt natural gas in the Ordos Basin, China

A significant amount of natural gas resources has been discovered in the Ordovician reservoirs under a thick layer of gypsum-salt strata as a result of ongoing research into deep natural gas in China's Ordos Basin, however, the genetic type and source of the Ordovician sub-salt natural gas remain contentious. These limits understanding how the geochemical properties of the natural gas in Ordos Basin have evolved and how to best guide future exploration and development. Based on the components, carbon and hydrogen isotopic ratios of natural gas from the latest exploration wells, combined with the geological background, this study systematically analyzed the genetic types and sources of sub-salt natural gas of the central and eastern Ordos Basin. The results show that the Ordovician natural gas is mainly composed of hydrocarbon gases with low content of heavy hydrocarbons and dryness (CCH4/CCH4+) above 0.95, belonging to typical dry gas. Non-hydrocarbon gases mainly include N2 and CO2, and some natural gas samples contained H2S. The Ordovician sub-salt natural gas is primarily a self-generating and self-preserving oil-cracking gas with relatively high maturity (Ro ranging from 1.5% to 2.1%) mixed with coal-derived gas generated from upper-Paleozoic coal with relatively low maturity (Ro ranging from 1.1% to 1.5%). Due to the dual-source hydrocarbon supply, the Ordovician sub-salt reservoirs provide favorable gas accumulation conditions and development prospects. This study offers a reasonable explanation for the anomalous geochemical characteristics of the Ordovician sub-salt reservoirs in the Ordos Basin, and also may serve as a guide for future exploration of natural gas in the carbonate gypsum-salt sedimentary system in other basins.