New α-keto acid-derived hydrazone ligands and their reaction with the {Re(CO)3}+

Aida Lorenzo,Saray Argibay-Otero,Carlos Platas-Iglesias,Ezequiel M. Vázquez-López

Polyhedron（2024）

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摘要

Two hydrazone ligands derived from pyruvic acid together with their rhenium(I) mononuclear complexes were synthesised. Besides, in the case of HL1 a trimeric complex is isolated and the dimer can be obtained from HL2. The study of the crystal structures and the calculation of vibrations by DFT are included.

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关键词

Rhenium,Hydrazone,α-ketoacid,Carbonyl complexes

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