Peptide coupling using recyclable bicyclic benziodazolone
CHEMICAL COMMUNICATIONS(2024)
摘要
We report a greener peptide coupling using bicyclic benziodazolone and triarylphosphine as coupling reagents. Bicyclic benziodazolone also works as a base and can be recovered as the corresponding iodine(i) compound after use, which can be converted to the original iodine(iii) reagent by electrolytic oxidation. This study provides a greener peptide coupling method using triarylphosphine and recyclable bicyclic benziodazolone, which acts as an oxidant for phosphine as well as base.
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