Adsorption and photodegradation of organic contaminants by silver nanoparticles: isotherms, kinetics, and computational analysis

In view of the widespread and distribution of several classes and types of organic contaminants, increased efforts are needed to reduce their spread and subsequent environmental contamination. Although several remediation approaches are available, adsorption and photodegradation technologies are presented in this review as one of the best options because of their environmental friendliness, cost-effectiveness, accessibility, less selectivity, and wider scope of applications among others. The bandgap, particle size, surface area, electrical properties, thermal stability, reusability, chemical stability, and other properties of silver nanoparticles (AgNPS) are highlighted to account for their suitability in adsorption and photocatalytic applications, concerning organic contaminants. Literatures have been reviewed on the application of various AgNPS as adsorbent and photocatalyst in the remediation of several classes of organic contaminants. Theories of adsorption have also been outlined while photocatalysis is seen to have adsorption as the initial mechanism. Challenges facing the application of silver nanoparticles have also been highlighted and possible solutions have been presented. However, current information is dominated by applications on dyes and the view of the authors supports the need to strengthen the usefulness of AgNPS in adsorption and photodegradation of more classes of organic contaminants, especially emerging contaminants. We also encourage the simultaneous applications of adsorption and photodegradation to completely convert toxic wastes to harmless forms.