Modification of physicochemical and electrical characteristics of lead sulfide (PbS) nanoparticles (NPs) by manganese (Mn) doping for electronic device and applications

In the present study, Pb1−xMnxS (0, 0.04, and 0.06) nanoparticles (NPs) were prepared by chemical co-precipitation process. The effects of Mn doping on the structural, morphological, vibrational, optical, and electrical characteristics of the PbS nanoparticles were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), Raman spectroscopy, UV–Vis spectroscopy, and I–V characteristics respectively. XRD patterns confirm the face-centered cubic (fcc) structure without impurity phases. The average crystalline size, unit cell constant, and porosity were found in the ranges of 11.93–14.33 nm, 5.7250–5.6888 Å, and 4.80–2.35