Variation in urban snow quality indicated by three seasonal sampling surveys conducted in Lule? (Sweden) within a span of 27 years
JOURNAL OF CONTAMINANT HYDROLOGY(2024)
Abstract
Concentrations of total suspended solids (TSS), trace metals (Cu, Cd, Cr, Zn, Cd, Pb), Na and 16 US EPA priority PAHs in urban snow were studied in the City of Lule & aring; in Northern Sweden. Snow was sampled at six central urban and suburban sites with various traffic intensities, in three sampling surveys (1994-95, 2002-03, 2020-21), repeated for three ages of the urban snow cover of 40, 80, and 120 days, respectively. The older data, from the 1994-95 and 2002-03 surveys, were obtained from the existing literature. The concentrations and mass loads of TSS and most trace metals studied (Zn, Cu, Pb, and Cd) varied with time. TSS, Zn, and Cu showed slightly higher concentrations and mass loads in the 2003 (TSS (avg) = 2300 mu g/L, Zn (avg) = 620 mu g/L and Cu (avg) = 250 mu g/L) and 2021 (TSS (avg) = 1500 mu g/L, Zn (avg) = 530 mu g/L and Cu (avg) = 220 mu g/L) sampling surveys, compared to the 1995 survey (TSS (avg) = 620 mu g/L, Zn (avg) = 240 mu g/L and Cu (avg) = 97 mu g/L). However, no evident trend was observed between the 2003 and 2021 sampling surveys. The highest concentrations of Pb and Cd were observed in snow samples from the 1994-95 sampling survey (Pb (max) = 570 mu g/L, Cd (max) = 4.6 mu g/L). Results indicated higher concentrations of the pollutants studied in the city centre, compared to the residential suburbs, and in areas with heavier traffic, where concentrations of metals correlated well with traffic intensity. Fractionation analysis of trace metals indicated that Zn, Cu and Pb occurred mostly in the particulate-bound phase (>0.45 mu m) containing the most of Zn, Cu, and Pb mass, at 80, 84 and 94% of the total, respectively. Over 50% of the dissolved phase of Zn and Cu was in the truly dissolved fraction (<3000 MWCO). Concentrations of PAHs also increased with traffic intensity, with pyrene being the most frequently detected PAH, likely because of the strength of sources and various physical processes influencing the snowbanks development and causing spatial and temporal variations in pollutant concentrations.
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Key words
Urban snow,Total suspended solids (TSS),Metals,PAHs,Metal fractionation
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