BN-Embedded Aromatic Hydrocarbon Synthesis via Nucleophilic Diboration Reactions

Mei Harada, Shota Fujioka, Shoma Ansai,Chao Wang,Shinichiro Kamino,Keiichi Hirano,Masanobu Uchiyama

ORGANIC LETTERS（2023）

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摘要

Activation of bis-(pinacolato)-diboron with aromatic lithium amide promotes diboration of the proximal C-C triple bond, leading to BN-embedded aromatic compounds. In situ treatment of the initially generated spirocyclic borate intermediate with aqueous acid or organometallic reagents enables ligand installation on the endocyclic boron atom.

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