High capacity and excellent cyclic performances of Mn 2 O 3 /Mn 3 O 4 /C materials as li-ion battery anode
Journal of Materials Science: Materials in Electronics(2024)
摘要
Due to the large volume change and poor conductivity, manganese oxide with high theoretical specific capacity is difficult to be widely used in the anode of lithium-ion battery. By the self-propagating sol–gel method, the nano-sized manganese oxide particles are embedded in the amorphous porous C in situ. Amorphous porous C and nano-manganese oxide particles can alleviate the volume effect of manganese oxide, and C can increase the conductivity and stability of Mn 2 O 3 /Mn 3 O 4 /C composites. Therefore, Mn 2 O 3 /Mn 3 O 4 /C composites have excellent cyclic properties: 902.9 mAh/g at 1.0 A/g after 1300 cycles; 290.5 mAh/g at 5.0 A/g after 10,000 cycles; 183.3 mAh/g at 10 A/g after 10,000 cycles.
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