Enhanced CO₂ reduction with hydrophobic cationic-ionomer layer-modified zero-gap MEA in acidic electrolyte

A hydrophobic cationic-ionomer layer of quaternary ammonium poly(N-methyl-piperidine-co-p-terphenyl) and PTFE is presented to enhance the CO2 electroreduction in a zero-gap membrane electrode assembly (MEA) electrolyzer under acidic and low alkali ion concentration conditions. The modified MEA achieved a maximum CO faradaic efficiency of 95.6% at 100 mA cm(-2).