MOF (UiO-66-NH₂)@COF (TFP-TABQ) hybrids via on-surface condensation reactions for sustainable energy storage

Core-shell MOF@COF hybrids were synthesized via subsequent modification of MOF UiO-66-NH2 with 1,3,5-triformylphloroglucinol (TFP) and 2,3,5,6-tetraaminobenzoquinone (TABQ). The hybrids exhibited significant surface area (236 m(2) g(-1)) and outstanding electrochemical performance (103 F g(-1) at 0.5 A g(-1)), surpassing both COFs and MOFs, thereby showcasing the potential of on-surface condensation reactions for developing high-performance energy storage devices.