Identification and quantification of nutrients sources in the Aspio watershed (Italy). Insight from geogenic mineralization and anthropogenic pressure

An accurate evaluation of river water quality could be challenging due to the complex hydrological and anthropogenic processes which affect its nature. Reliable water quality data are mandatory to identify long-term trends and regional variability at the watershed scale. In this study, a combined approach using time series, regression, and multivariate statistical analysis along with SWAT modelling was applied to identify the relevant hydrogeochemical processes and the nutrients sources within the Aspio watershed (Ancona, Italy). The analysis detected different processes: i) the geogenic origin of Cl- and SO42-, ii) the heavy metals (Cu and Ni) and hydrocarbons pollution due to runoff from urban and industrial areas, and iii) the agricultural contribution of pesticides, nitrogen, and phosphorous. A SWAT model was implemented to quantify the nutrients load in the Aspio river. A calibration for streamflow, river sediment yield, and for nutrients load was obtained considering agricultural, urban, and wastewater treatment plant contributions. Agriculture and treated wastewater contributed to the overall nitrogen load only for 4% and 12% respectively, while the majority was due to leakage from urban sewage (84%). A scenario with only fertilizers' load (excluding other sources) highlighted that nitrogen and phosphorous export from agricultural lands did not significatively impact the Aspio river. The spatial representation of runoff susceptibility also showed how the highest susceptibility for nitrogen and phosphorous loads is due to areas located close to urban settlements.