Ionic liquid-assisted synthesis of N, F, and B co-doped BiOBr/Bi2Se3 on Mo2CTx for enhanced performance in hydrogen evolution reaction and supercapacitors
Journal of Colloid and Interface Science(2024)
Abstract
Heteroatom doping and heterojunction formation are effective strategies to enhance electrochemical performance. In this study, we present a novel approach that utilizes an ionic liquid-assisted synthesis method to fabricate a BiOBr-based material, which is subsequently loaded onto Mo2CTx via a selenization treatment to create a BiOBr/Bi2Se3 heterostructure, denoted as NBF-BiOBr/Bi2Se3/Mo2CTx. The incorporation of heteroatoms improves its hydrophilicity and electronegativity, while the formation of heterojunctions adjusts the electronic structure at the interface, resulting in lower OH-/H+ adsorption energy. The specific surface area of NBF-BiOBr/ Bi2Se3/Mo2CTx is 193.1 m2/g. In hydrogen evolution reaction (HER) tests, NBF-BiOBr/Bi2Se3/Mo2CTx exhibits exceptional catalytic performance in acidic media, requiring only an overpotential of 109 mV to achieve a current density of 10 mA cm-2. Furthermore, NBF-BiOBr/Bi2Se3/Mo2CTx demonstrates superior electrochemical performance in an asymmetric supercapacitor, with an energy density as high as 55.6 Wh kg-1 at a power density of 749.9 Wh kg 1. This work provides a novel approach for heteroatom doping and heterojunction synthesis, offering promising prospects for further advancements in the field.
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Key words
Ionic liquid,BiOBr,Hydrogen evolution,Supercapacitors
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