UV irradiation induced simultaneous reduction of Cu(II) and degradation of EDTA in Cu(II)-EDTA in wastewater containing Cu(II)-EDTA

Decomplexation of Cu(II)-EDTA followed by chemical precipitation of free Cu(II) ions can effectively degrade EDTA in Cu(II)-EDTA and remove Cu(II), but requires large precipitant dosage and inevitably produces a large amount of copper-containing sludge that is difficult to deal with. Herein, we demonstrated that simultaneous reduction of Cu(II) and degradation of EDTA in Cu(II)-EDTA can be achieved by UV irradiation of wastewater containing Cu(II)-EDTA without adding reagent. 93.65% of Cu(II) was reduced to Cu(0) with a high purity of 99.93 wt%, which can be recycled, thus avoiding the generation of copper-containing sludge. 96.67% of EDTA in Cu(II)-EDTA was degraded, and the final products were HCHO, NH4+, NO3- and low-molecular acids. In depth, the dominant degradation mechanism of EDTA in Cu(II)-EDTA was photo-induced successive decarboxylation through homolysis of C-O and C-C bond of -CH2-COOH group, followed by ligand to metal charge transfer (LMCT) and hydrolysis reactions. The minor degradation mechanism of EDTA in Cu(II)-EDTA was successive decarboxylation by center dot OH radicals. Simultaneously, Cu(II) was reduced to Cu(0) by H center dot and eaq - produced by UV irradiation of Cu(II)-EDTA. This study provided an approach of simultaneous removal of heavy metals and degradation of EDTA in Cu(II)-EDTA in wastewater containing heavy metal-EDTA complex.