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Mechanistic Understanding of Metal–acid Synergetic Hydroconversion of Polyethylene under Mild Conditions over a Ru/MOR Catalyst

Ruizhe Chen,Leilei Cheng,Jing Gu,Haoran Yuan,Yong Chen

ENERGY CONVERSION AND MANAGEMENT（2024）

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Abstract
•Milled Ru/MOR with high metal–acid accessibility promotes LDPE hydroconversion.•Liquid fuel and CH4 production are sensitive to Ru size and Brønsted acidity.•Ru size determines the process of hydrogenolysis and hydrocracking reaction.•The effect of metal–acid synergy on terminal/internal deconstruction is unveiled.
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Key words
Plastic waste,Bifunctional catalysts,Ru size,Hydrogenolysis,Hydrocracking
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