Depositional characteristics of fine-grained sedimentary rocks and the links to OAE-3 and PETM of the Upper Cretaceous-Paleogene Madingo Formation, lower Congo Basin, West Africa

Fine-grained sedimentary rocks of the Madingo Formation in the Lower Congo Basin (LCB), are significant targets for Upper Cretaceous-Paleogene depositional system analysis in West Africa. Six types of fine-grained sedimentary rocks of the Madingo Formation were identified based on integrated analyses of petrographic characteristics, geochemical element analysis and electron back-scattered diffraction of thin sections, including (1) siliceous mudstone, (2) claystone, (3) marlstone, (4) radiolarian-rich mudstone, (5) foraminifera-rich mudstone, and (6) phosphatic mudstone. Geochemical indexes (U/Th, V/(V + Ni), V/Cr, and Ni/Co) indicate that the Madingo Formation on the deep-water slope was characterized by typical oxygen-poor and even anaerobic environment, preserving organic matter and thus preserving sediments with relatively high TOC, abundant marine fossils and framboidal pyrite. The LCB experienced two different marginal marine environments during the deposition of the Madingo Formation. The lower Madingo Formation was characterized by a radiolarian-rich mudstone (the first stage of upwelling) deposited in a marginal semi-restricted sea bay environment (correlated with the Coniacian-Santonian Oceanic Anoxic Event 3; OAE-3), with up to 4.0% TOC, and types II2 and II1 organic matter. The upper Madingo Formation was characterized by foraminifera-rich and phosphatic mudstone (the second stage of upwelling) deposited in a marginal open marine environment (correlated with the Paleocene-Eocene Thermal Maximum; PETM), with up to 4.83% TOC and 5.0 mg/g phosphate that is rich in types I and II1 organic matter. The whole Madingo deposition is estimated to have spanned a 52-Myr period, and the low sediment accumulation rate of approximately 9 mu m/yr can lead to a high TOC content. The three identified condensed sections include radiolarian-rich, foraminifera-rich or phosphatic mudstones that deposited in the deep-water slope, were probably marine source rocks for post-salt exploration in West Africa.