Alkynylation of Aldehydes Initiated by Cathodic Reduction

CHEMELECTROCHEM(2024)

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Abstract
Alkynylation of aldehydes initiated by cathodic reduction was performed. The cathodic alkynylation required only a semi-catalytic amount of electricity to consume the starting material completely. Cyclic voltammetry and some control experiments suggest that the electron-generated base derived from the cathodic reduction of benzaldehyde promotes alkynylation. Alkynylation of aldehydes initiated by cathodic reduction was performed. The cathodic alkynylation required only a semi-catalytic amount of electricity to consume the starting material completely. Cyclic voltammetry and some control experiments suggest that the electron-generated base derived from the cathodic reduction of benzaldehyde promotes alkynylation.image
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Key words
Alkynylation,Catalytic electrolysis,Cathodic reduction,Electrochemical synthesis,Trimethylsilylacetylene
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