Regio- and stereoselective syntheses of chiral α-quaternary (Z)-trisubstituted allylic amino acids via synergistic Pd/Cu catalysis
Chemical Communications（2023）
Abstract
Synergistic palladium/copper catalysis for asymmetric allylic alkylation of vinylethylene carbonates with aldimine esters has been developed for the synthesis of α-quaternary ( Z )-trisubstituted allylic acids with high efficiency under mild conditions.
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Key words
pd/cu catalysis,stereoselective syntheses,amino acids
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