Highly diastereo- and enantioselective copper-catalyzed methylboration of 1,2-dihydroquinolines and 2H-chromenes
Organic chemistry frontiers(2023)
Abstract
A Cu-catalyzed asymmetric methylboration of 1,2-dihydroquinolines, 2 H -chromenes and 2 H -thiochromenes providing boryl products bearing two adjacent chiral centers with excellent selectivities, up to 99 : 1 dr and 99.9% ee, has been realized for the first time.
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Key words
copper-catalyzed
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