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Electrophilic and nucleophilic gas phase reactivity of the Janus cluster-based anions [{Mo6Cl8}Cl5□] (□ = lacuna)

Chemical Communications(2023)

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摘要
The Janus-reactivity character of the monoanion [{Mo 6 Cli8}Cla5□ a ] − that leads to an unprecedented self-reactivity is proved by CID-MS-MS and quantum chemical studies.
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关键词
nucleophilic gas phase reactivity,anions,electrophilic,cluster-based
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