Back Cover: Ligand‐Free Ultrasmall Recyclable Iridium(0) Nanoparticles for Regioselective Aromatic Hydrogenation of Phosphine Oxide Scaffolds: An Easy Access to New Phosphine Ligands

Gaspard Hedouin,Sudripet Sharma,Karanjeet Kaur,Ramesh Hiralal Choudhary,Jacek B. Jasiński,Fabrice Gallou,Sachin Handa

Angewandte Chemie International Edition（2023）

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摘要

Heterogeneous and recyclable ligand-free nanoparticles of iridium(0) enabled highly selective hydrogenation of distal unsubstituted aromatic rings to generate novel phosphine ligands. The iridium-hydride species and hydrogen bonding between the substrate and solvent facilitate the catalysis, as reported by Fabrice Gallou, Sachin Handa et al. in their Research Article (e202307139).

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phosphine oxide scaffolds,new phosphine ligands,regioselective aromatic hydrogenation,nanoparticles

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