Catalytic oxidation properties of an acid-resistant cross-bridged cyclen Fe(ii) complex. Influence of the rigid donor backbone and protonation on the reactivity

Jean‐Noël Rebilly,Christian Herrero,Katell Sénéchal‐David,Régis Guillot,Frédéric Banse

Dalton Transactions（2023）

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摘要

The inertness of an Fe II complex supported by a cross-bridged ligand is partly reduced under acidic conditions which enhances its reactivity with H 2 O 2 and its performance in oxidation catalysis.

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关键词

catalytic oxidation properties,rigid donor backbone,fe<scp>ii</scp>,acid-resistant,cross-bridged

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