PNP-type ligands enabled copper-catalyzed N-formylation of amines with CO₂ in the presence of silanes

Zijie Song, Jun Liu,Shuya Xing,Xinxin Shao,Jiayun Li,Jiajian Peng, Ying Bai

Organic and Biomolecular Chemistry（2023）

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摘要

The sustainable catalytic transformation of carbon dioxide into fine chemicals with high efficiency is a global challenge as although CO 2 is an abundant, nontoxic, and sustainable carbon feedstock but also a critical factor for the Greenhouse Effect.

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ligands,amines,pnp-type,copper-catalyzed

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PNP-type ligands enabled copper-catalyzed N-formylation of amines with CO2 in the presence of silanes

PNP-type ligands enabled copper-catalyzed N-formylation of amines with CO₂ in the presence of silanes