Near room temperature stepwise spin state switching and photomagnetic effect in a mixed-valence molecular square

Sujit Kamilya,Sakshi Mehta,Rodrigue Lescouëzec,Yanling Li,Jiří Pěchoušek,Mohini Semwal,Abhishake Mondal

Dalton Transactions（2023）

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摘要

Two-step thermo-induced spin-state switching was observed in a mixed-valence [Fe 2 Fe 2 ] molecular square complex. The desolvated sample exhibits ON/OFF photo switching and reversible spin-state switching with lower T1/2 value.

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关键词

stepwise spin state switching,photomagnetic effect,molecular square,mixed-valence

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