Characterization and magnetic properties of two mixed-valence compounds A2MnⅡMn2III(SeO3)6 (A = Sr and Ba)

Changke Lu,Yuanjun Zhang,Meiyan Cui,Zhiying Zhao,Zhangzhen He

Journal of Magnetism and Magnetic Materials（2023）

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摘要

•Two mixed-valence manganese based compounds A2MnⅡMn2III(SeO3)6 (A = Sr and Ba) are obtained by hydrothermal method.•These compounds exhibit Mn3+ ions located in a distorted honeycomb motif centred by the Mn2+ ions.•These compounds show a short-range and a long-range antiferromagnetic order at low temperature.•These compounds show a metamagnetic transition under applied fields.

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关键词

Selenite,Mixed-valence,Hydrothermal synthesis,Magnetic properties

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