Synthesis of 2-Indolyl C-Glycoside Neopetrosins A and C and Congeners via Ni-Catalyzed Photoreductive Cross-Coupling

Xin Yan,Yingjie Wang,Zhaolun Zhang,Tayyab Gulzar,Yuqi Lin,Jing Wang,Dapeng Zhu,Biao Yu

Organic Letters（2023）

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摘要

The synthesis of neopetrosins A and C, two 2-indolyl C-α-d-mannopyranosides, and their congeners has been realized via a direct Ni/photoredox-catalyzed reductive coupling of 3-methoxycarbonyl-2-iodo-1H-indoles with pyranosyl bromides.

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关键词

synthesis,ni-catalyzed,cross-coupling

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