Structural changes induced by electric currents in a single crystal of Pr2CuO4

We demonstrate an approach to the structural and electronic property modification of perovskites, focusing on ${\mathrm{Pr}}_{2}\mathrm{Cu}{\mathrm{O}}_{4}$, an undoped parent compound of a class of electron-doped copper-oxide superconductors. Currents were passed parallel or perpendicular to the copper oxygen layers with the voltage ramped up until a rapid drop in the resistivity was achieved, a process referred to as ``flash.'' The current was then further increased tenfold in current-control mode. This state was quenched by immersion into liquid nitrogen. Flash can drive many compounds into different atomic structures with new properties, whereas the quench freezes them into a long-lived state. Single-crystal neutron diffraction of as-grown and modified ${\mathrm{Pr}}_{2}\mathrm{Cu}{\mathrm{O}}_{4}$ revealed a $\sqrt{10}\ifmmode\times\else\texttimes\fi{}\sqrt{10}$ superlattice due to oxygen-vacancy order. The diffraction peak intensities of the superlattice of the modified sample were significantly enhanced relative to the pristine sample. Raman-active phonons in the modified sample were considerably sharper. Measurements of electrical resistivity, magnetization, and two-magnon Raman scattering indicate that the modification affected only the Pr-O layers, but not the Cu-O planes. These results point to enhanced oxygen-vacancy order in the modified samples well beyond what can be achieved without passing electrical current. Our work opens a new avenue toward electric field/quench control of structure and properties of layered perovskite oxides.