Bifunctional Thiourea-Based Organocatalysts Promoted Kinetic Resolution Polymerization of Racemic Lactide to Isotactic Polylactide

Jiang Dai,Wei Xiong,Dongyu Li,Zhongzheng Cai,Jian‐Bo Zhu

Chemical Communications（2023）

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摘要

We designed a series of bifunctional thiourea-based organocatalysts by combining two stereogenic elements, which promoted kinetic resolution polymerization of racemic lactide to produce isotactic polylactide with P m up to 0.96.

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关键词

kinetic resolution polymerization,isotactic polylactide,thiourea-based

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