Small-sized nitride phosphors achieving mini-LED backlights with superhigh brightness and ultralong durability

High brightness mini-LED backlit displays attract extensive advanced applications. However, it is a challenge to develop small-sized phosphors concurrently satisfying high brightness and long-term durability to accommodate mini-LED chips. Herein, a two-step facile approach combining high temperature sintering and mechanochemical milling is proposed to obtain small-sized 13-Sialon:Eu nitride phosphors (D50 = 3.13 lm) with a five-fold increase in quantum efficiency (QE, 16% 79%) and a superb on chip durability with 100% maintenance of QE for 1400 h. The high performance is attributed to the increased Eu2+ percentage (67% 77%) and the unaltered chemical stiffness after the mechanochemical processing. Crucially, 13-Sialon:Eu film made from small-sized powders shows higher packaging density and better light uniformity, concomitantly with an improved QE of 83%. Moreover, this approach is generally applicable to other robust nitride phosphors. By using small-sized 13-Sialon: Eu and (Sr,Ca)AlSiN3:Eu films, as-fabricated mini-LED backlights simultaneously achieve a superhigh brightness of 302,150 nits and an ultralong durability exceeding 2,000 h, opening up an avenue for mini-LED backlit displays being a viable technology for high-end applications.