Visible-light induced C(sp3)–H arylation of glycine derivatives by cerium catalysis

Shutao Wang,Yanjie Ye,Hailong Shen,Ji-Yu Liu, Liang Zhao, Zhen Jiang,Junqiang Lei, Zhimin Yuan

Organic and Biomolecular Chemistry(2023)

Cited 2|Views4
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Abstract
A Ce(III)-catalyzed, visible-light induced aerobic oxidative dehydrogenative coupling reaction between glycine derivatives and electron-rich arenes is disclosed. The protocol proceeds efficiently under mild conditions, providing an efficient method for the rapid synthesis of α-arylglycine derivatives without the need for an external photosensitizer and additional oxidant. Moreover, this protocol could be performed on a 5 mmol scale, without obvious reduction of the efficiency.
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Key words
glycine derivatives,catalysis,arylation,visible-light
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