Construction of 1,2-cis rhamnosidic linkages and synthesis of core tetrasaccharide repeating unit of Streptococcus pneumoniae serotype 23F

Jiaming Ao,Xiaoya Zhao,Siai Zhou,Yajing Guo, Guoqing Wang,Shiuh-Bin Fang,Xuewen Yao,Yuhua Liu,Akihiro Ishiwata,Katsunori Tanaka,Feiqing Ding,Hui Cai

Organic chemistry frontiers（2023）

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摘要

An effective ZnI 2 -mediated 1,2- cis - l -rhamnosylation strategy was achieved by employing a 2,3- O -( o -xylylene) rhamnose donor, and applied to assemble the core repeating tetrasaccharide unit of the S. pneumoniae 23F capsule polysaccharide.

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rhamnosidic linkages,synthesis

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