Surface species in direct liquid phase synthesis of dimethyl carbonate from methanol and CO₂: an MCR-ALS augmented ATR-IR study

Matteo Signorile,Davide Salusso,Valentina Crocellà,Maria Cristina Paganini,Silvia Bordiga,Francesca Bonino,Davide Ferri

Physical Chemistry Chemical Physics（2023）

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摘要

The reaction mechanism of CO 2 and methanol toward dimethyl carbonate over ZrO 2 in the liquid phase is elucidated by means of ATR-IR augmented by MCR-ALS analysis.

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direct liquid phase synthesis,dimethyl carbonate,methanol,mcr-als

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Surface species in direct liquid phase synthesis of dimethyl carbonate from methanol and CO2: an MCR-ALS augmented ATR-IR study

Surface species in direct liquid phase synthesis of dimethyl carbonate from methanol and CO₂: an MCR-ALS augmented ATR-IR study