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Direct observation of highly effective hydrogen isotope separation at active metal sites by in situ DRIFT spectroscopy

Xiayan Yan, Yu Song,Degao Wang,Tifeng Xia,Xinxin Tan,Jingwen Ba,Tao Tang,Wenhua Luo,Shenguang Ge,Renjin Xiong

Chemical Communications（2023）

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Abstract
In situ DRIFT spectroscopy was developed to observe the preferential adsorption of D 2 over H 2 at active Cu I sites to show the chemical affinity quantum sieving effect for hydrogen isotope separation in microporous adsorbents.
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Key words
effective hydrogen isotope separation,drift spectroscopy,active metal sites
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