Solubilized LiNO₃ by the cationic size effect of CsF for lithium metal anode protection and dendrite formation prevention in carbonate electrolyte

Jing Zhao,Zhengwei Wan,Xiaomin Zhang,Miaomiao Tian,Kun Wang, Xinyu Chen,Min Ling,Wenbin Ni,Chengdu Liang

Inorganic chemistry frontiers（2023）

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摘要

CsF solubilized LiNO 3 to optimize solvated shell of Li + in carbonate electrolyte. LiF-rich SEI was generated to prevent severe side reactions of Li metal. Cs + can inhibit lithium dendrite formation by self-healing electrostatic shield mechanism.

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关键词

lithium metal anode protection,electrolyte,carbonate,dendrite formation prevention

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Solubilized LiNO3 by the cationic size effect of CsF for lithium metal anode protection and dendrite formation prevention in carbonate electrolyte

Solubilized LiNO₃ by the cationic size effect of CsF for lithium metal anode protection and dendrite formation prevention in carbonate electrolyte