Inhibition of the P3–O3 phase transition via local symmetry tuning in P3-type layered cathodes for ultra-stable sodium storage

Yanan Zhou,Zichun Xiao,Duzhao Han,Suning Wang,Jinniu Chen,Wei Tang,Mingyu Yang, Lang Shao,Chengyong Shu,Weibo Hua,Dezhong Zhou,Yuping Wu

Journal of materials chemistry. A, Materials for energy and sustainability（2023）

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摘要

We reconfigure the sodiation/desodiation process of P3-type layered cathodes by a local symmetry tuning strategy to enhance their stability. The cathodes exhibit long-term cycling stability with a higher capacity retention of 74% after 2000 cycles at 1C.

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关键词

p3–o3 phase transition,cathodes,sodium,phase transition,ultra-stable

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