(Et₄N)[W^III(DAPBH)(CN)₂], the first pentagonal-bipyramidal W(iii) complex with unquenched orbital angular momentum: a novel Ising-type magnetic building block for single-molecule magnets

Yu. V. Manakin, V. S. Mironov, Т. А. Баженова, I. A. Yakushev, I. F. Gilmutdinov, Sergey V. Simonov,Eduard B. Yagubskii

Chemical Communications（2023）

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摘要

The first pentagonal-bipyramidal tungsten(III) complex (Et4N)[WIII(DAPBH)(CN)2] with a N3O2-type Schiff-base ligand and two apical cyanide groups was synthesized and characterized structurally and magnetically. The complex has a low-spin (S = 1/2) ground state and features unquenched orbital angular momentum ML = ±1 causing very strong Ising-type magnetic anisotropy.

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关键词

unquenched orbital angular momentum,magnetic building block,pentagonal-bipyramidal,ising-type,single-molecule

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(Et4N)[WIII(DAPBH)(CN)2], the first pentagonal-bipyramidal W(iii) complex with unquenched orbital angular momentum: a novel Ising-type magnetic building block for single-molecule magnets

(Et₄N)[W^III(DAPBH)(CN)₂], the first pentagonal-bipyramidal W(iii) complex with unquenched orbital angular momentum: a novel Ising-type magnetic building block for single-molecule magnets