Effect of Gd doping on phase evolution, mechanical and thermal characteristics of 1La-xGd-2Yb-3.5YSZ solid solutions

Thermal barrier coatings (TBCs) are critical for the reliability and lifespan of aircraft engine turbine blades. In this study, a novel quaternary rare-earth oxide (La2O3, Gd2O3, Yb2O3, and Y2O3) co-doped ZrO2 solid solution, referred to as 1La-xGd-2Yb-3.5YSZ, was synthesized by varying the doping amount of Gd2O3 from 0 to 6 mol. %. The impact of co-doping-induced lattice distortion on the phase composition, high-temperature phase stability, sintering resistance, and mechanical and thermal properties of the solid solution has been explored. It is found that the addition of Gd2O3 stabilizer effectively increased the lattice distortion of the solid solution, which led to improved phase stability and sintering resistance, enhanced mechanical properties, and low thermal conduc-tivity. Our findings highlight the promising properties of the 1La-xGd-2Yb-3.5YSZ solid solution, making it an attractive candidate for TBC materials.