Palladium-Catalyzed Enantioselective Indole Allylic Alkylation with Chiral Phosphoramidite-Selenide-Based Ligands
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(2024)
摘要
Environmental Engineering Organic Hybrid Functionalized Materials A Pd/phosphoramidite-selenide-catalyzed highly enantioselective C-3 allylic alkylation with a wide range of indole nucleophiles has been developed, giving the corresponding products with up to 95 % yield and 99 % ee. A convenient Pd-catalyzed allylic alkylation of indoles was developed using a P-Se ligand, and the scope of the reaction was demonstrated with various substituted indoles. The corresponding products were obtained in good to excellent yields (up to 95 %) and up to 99 % ee.image
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关键词
allylic alkylation,asymmetric synthesis,chiral ligand,palladium catalysis,phosphoramidite-selenide
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