Rücktitelbild: A Photosensitizing Metal–Organic Framework as a Tandem Reaction Catalyst for Primary Alcohols from Terminal Alkenes and Alkynes (Angew. Chem. 35/2023)

Angewandte Chemie(2023)

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摘要
A photosensitizing covalent metal–organic framework (CMOF) was prepared as a tandem reaction catalyst by Guo-Hong Ning, Dan Li, and co-workers in their Research Article (e202306497). By combining Cu-CTUs as metal-catalytic sites and Bodipy linkers as photosensitizers, this CMOF can catalyze terminal alkenes and alkynes to produce primary alcohols via one-pot tandem reactions with excellent regioselectivity, good overall yields for two-step reactions, broad substrate compatibility and good reusability under mild conditions.
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关键词
tandem reaction catalyst,photosensitizing metal–organic,terminal alkenes,alkynes
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