Application of Polypropylene carbonate for the tape casting of silicon nitride ceramics

Abstract QPAC40 (polypropylene carbonate), with a little decomposition residue, is commonly used as a binder in aluminum nitride (AlN) tape casting. In this paper, we tried to explore its application in silicon nitride (Si 3 N 4 ) tape casting. By studying the influence of dispersant, binder, plasticizer/binder ratio, and solid loading on slurry and green tape properties, the optimum formulation of the tape casting of Si 3 N 4 slurry was determined, and the green tape with a uniform structure and relative density up to 63.16% was prepared. Si 3 N 4 ceramics were obtained by debinding at 600°C for 1 h in vacuum and gas‐pressure sintering at 1830°C for 2 h in N 2 . The thermal conductivity and flexural strength of Si 3 N 4 ceramics were 56.28 ± 1.21 W/(m·K) and 1130.67 ± 23.58 MPa, respectively. These results indicated that QPAC40 can be used to prepare Si 3 N 4 sheets through tape casting.