Divergent synthesis of bis(indolyl)methanes via Fe^III-catalysed regioselective dehydrogenative coupling reactions: a biomimetic approach to 6,6′-bis-(debromo)-gelliusine F

Yan Wu,Moude Liu, Qing Wang, Hua Tian,Jinbao Fan,Yingjun Zhou,Yajing Wang,Xu Deng

Organic and Biomolecular Chemistry（2023）

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摘要

An Fe III -catalyzed divergent and regioselective dehydrogenative coupling reaction of readily available tryptamines to efficiently access 2,8′- and N1,8′-bisindoles is reported.

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regioselective dehydrogenative coupling reactions,divergent synthesis

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Divergent synthesis of bis(indolyl)methanes via FeIII-catalysed regioselective dehydrogenative coupling reactions: a biomimetic approach to 6,6′-bis-(debromo)-gelliusine F

Divergent synthesis of bis(indolyl)methanes via Fe^III-catalysed regioselective dehydrogenative coupling reactions: a biomimetic approach to 6,6′-bis-(debromo)-gelliusine F