Producing circularly polarized luminescence by radiative energy transfer from achiral metal-organic cage to chiral organic molecules

The development of circularly polarized luminescence (CPL) materials with high performance is significantly important. Herein, we develop a facial strategy for fabricating a CPL -active system by employing an achiral luminescent metal -organic cage (MOC) and chiral boron dipyrromethene (BODIPY) molecules. CPL is achieved by taking advantage of the radiative energy transfer process, in which BODIPY molecules act as energy acceptors and MOCs act as donors. The CPL performance (maximum luminescence dissymmetry factor up to +/- 1.5 x10 -3 ) can be tuned by adjusting the ratio between MOCs and BODIPY. White -light emission with the CPL feature is obtained by using a ternary system including MOC, chiral BODIPY, and Rhodamine B. The present work provides a facile and universal strategy to construct a CPL -active system by integrating achiral luminophores and chiral molecules. (c) 2024 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.